Fragile‐to‐Strong Transition in Phase‐Change Material Ge <sub>3</sub> Sb <sub>6</sub> Te <sub>5</sub>

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چکیده

Chalcogenide phase-change materials combine a remarkable set of properties that makes them promising candidates for future non-volatile memory applications. Binary data storage exploits the high contrast in electrical and optical between covalent amorphous metavalent crystalline phase. Here authors perform an analysis liquid phase kinetics material Ge3Sb6Te5, which is key to ultrafast switching speeds. By employing four experimental techniques, viscosity measured over sixteen orders magnitude despite its propensity fast crystallization. These measurements reveal undergoes transition viscosity–temperature dependence associated with liquid–liquid transition. The system exhibits shallow change temperature near glass stabilizes cells state limits severity relaxation processes. Meanwhile, when heated during writing process, fragility increases more than double, causing drop rapidly enabling nanosecond crystallization speed. This highly unusual among forming liquids reminiscent behavior water. also technological success computer

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ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2022

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202202714